Rotational spectroscopy of the SrNH2 and SrND2 radicals ( X̃2A1 )

J. M. Thompsen, P. M. Sheridan, L. M. Ziurys

Research output: Contribution to journalArticle

5 Scopus citations

Abstract

The pure rotational spectrum of the SrNH2 radical in its X̃2A1 state has been recorded using sub-millimeter direct absorption techniques in the range 225-540 GHz. Measurements of SrND2 have also been conducted. Both molecules were produced by the reaction of metal vapor and NH3 or ND3. Fourteen and fifteen rotational transitions were recorded for SrNH2 and SrND2, respectively. Asymmetry doublets for Ka=0 through 5 or 6, as well as fine structure splittings, were observed in every transition. From these data, spectroscopic constants have been determined, as well as an r0-structure. This study provides additional evidence that SrNH2 is planar with ionic bonding.

Original languageEnglish (US)
Pages (from-to)373-382
Number of pages10
JournalChemical Physics Letters
Volume330
Issue number3-4
DOIs
StatePublished - Nov 10 2000

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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