Routine low-damage apatite U-Pb dating using laser ablation-multicollector- ICPMS

Stuart N. Thomson, George E Gehrels, Joaquin Ruiz, Robert Buchwaldt

Research output: Contribution to journalArticle

91 Citations (Scopus)

Abstract

Apatite is a common U-bearing accessory mineral with a U-Pb closure temperature of ∼500C, making U-Pb dating of apatite a potentially valuable thermochronometer. However, its low U concentration and tendency to incorporate common lead has limited widespread application to destructive isotope dilution methods. We overcome previous limitations by using a Nu Plasma multicollector ICPMS with an attached short-pulse excimer laser, and by identifying two new matrix-matched reference apatites to correct for elemental fractionation: gem-quality 485 Myr old apatite from Madagascar which we independently characterized by ID-TIMS analysis, and 523.5 Ma apatite from the McClure Mountain syenite (source of the 40Ar/ 39Ar reference MMhb). Common Pb is corrected using measured 204Pb isobarically corrected for Hg interference and a five-step iterative process using Stacey and Kramers' common Pb model. We accurately reproduce ages of numerous independently characterized apatites, regularly achieving precision of <2% (2σ) by pooling as few as five 30 m spot analyses. Data quality in apatite with low U concentrations, low 206Pb/ 204Pb values (<∼30) and young ages (<∼75 Ma) is compromised by the goal of avoiding significant grain damage. Such limitations can be overcome by using spot sizes 65 m or greater, but at the expense of substantial grain damage. For single detrital apatite grains with ages of ∼500 Ma, precision of <4% (2σ) was achieved by pooling 2 to 3 spots per grain. The accuracy of our detrital results is supported by a good age match with similar closure temperature 40Ar/ 39Ar detrital hornblende ages from the same sediment.

Original languageEnglish (US)
Article numberQ0AA21
JournalGeochemistry, Geophysics, Geosystems
Volume13
Issue number1
DOIs
StatePublished - 2012

Fingerprint

Apatites
Laser ablation
apatites
dating
ablation
apatite
laser ablation
laser
damage
closure temperature
closures
Bearings (structural)
Madagascar
syenite
Gems
accessory mineral
accessories
Accessories
Excimer lasers
Fractionation

Keywords

  • apatite dating
  • geochronology
  • LA-ICPMS

ASJC Scopus subject areas

  • Geochemistry and Petrology
  • Geophysics

Cite this

Routine low-damage apatite U-Pb dating using laser ablation-multicollector- ICPMS. / Thomson, Stuart N.; Gehrels, George E; Ruiz, Joaquin; Buchwaldt, Robert.

In: Geochemistry, Geophysics, Geosystems, Vol. 13, No. 1, Q0AA21, 2012.

Research output: Contribution to journalArticle

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