SILOXANE MODIFIED SiO//2-TiO//2 GLASSES VIA SOL-GEL.

C. S. Parkhurst, W. F. Doyle, L. A. Silverman, S. Singh, M. P. Andersen, D. McClurg, G. E. Wnek, Donald R Uhlmann

Research output: Chapter in Book/Report/Conference proceedingConference contribution

30 Citations (Scopus)

Abstract

Polydimethylsiloxane left bracket PDMS right bracket -modified SiO//2-TiO//2 glasses have been prepared via the sol-gel route. Polymer compositions varied between 17 and 67 wt% PDMS of molecular weights 1,700 and 36,000. Also varied was the Si/Ti ratio for a given polymer content and the nature of the Ti alkoxide. A general synthetic procedure made optically clear samples. Dense monolithic structures were obtained at room temperature for all compositions. The room temperature densification is attributed to relaxation and flow due to the presence of the polymer. The effects on properties of the overall composition and molecular weight of the polymer are reported implications in terms of structural models are considered.

Original languageEnglish (US)
Title of host publicationMaterials Research Society Symposia Proceedings
PublisherMaterials Research Soc
Pages769-773
Number of pages5
Volume73
ISBN (Print)0931837391
StatePublished - 1986
Externally publishedYes

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Polymers
Chemical analysis
Molecular weight
Polydimethylsiloxane
Densification
Sol-gels
Glass
Temperature

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

Parkhurst, C. S., Doyle, W. F., Silverman, L. A., Singh, S., Andersen, M. P., McClurg, D., ... Uhlmann, D. R. (1986). SILOXANE MODIFIED SiO//2-TiO//2 GLASSES VIA SOL-GEL. In Materials Research Society Symposia Proceedings (Vol. 73, pp. 769-773). Materials Research Soc.

SILOXANE MODIFIED SiO//2-TiO//2 GLASSES VIA SOL-GEL. / Parkhurst, C. S.; Doyle, W. F.; Silverman, L. A.; Singh, S.; Andersen, M. P.; McClurg, D.; Wnek, G. E.; Uhlmann, Donald R.

Materials Research Society Symposia Proceedings. Vol. 73 Materials Research Soc, 1986. p. 769-773.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Parkhurst, CS, Doyle, WF, Silverman, LA, Singh, S, Andersen, MP, McClurg, D, Wnek, GE & Uhlmann, DR 1986, SILOXANE MODIFIED SiO//2-TiO//2 GLASSES VIA SOL-GEL. in Materials Research Society Symposia Proceedings. vol. 73, Materials Research Soc, pp. 769-773.
Parkhurst CS, Doyle WF, Silverman LA, Singh S, Andersen MP, McClurg D et al. SILOXANE MODIFIED SiO//2-TiO//2 GLASSES VIA SOL-GEL. In Materials Research Society Symposia Proceedings. Vol. 73. Materials Research Soc. 1986. p. 769-773
Parkhurst, C. S. ; Doyle, W. F. ; Silverman, L. A. ; Singh, S. ; Andersen, M. P. ; McClurg, D. ; Wnek, G. E. ; Uhlmann, Donald R. / SILOXANE MODIFIED SiO//2-TiO//2 GLASSES VIA SOL-GEL. Materials Research Society Symposia Proceedings. Vol. 73 Materials Research Soc, 1986. pp. 769-773
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