Single chain polymer nanoparticles via sequential ATRP and oxidative polymerization

Philip T. Dirlam, Hyo Ju Kim, Kyle J. Arrington, Woo Jin Chung, Rabindra Sahoo, Lawrence J. Hill, Philip J. Costanzo, Patrick Theato, Kookheon Char, Dong-Chul Pyun

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

The synthesis of single chain nanoparticles has been achieved by the synthesis of a linear polystyrenic precursor carrying 3,4- propylenedioxythiophene groups via atom transfer radical polymerization followed by intramolecular crosslinking via oxidative polymerization. This methodology enabled the introduction of electroactive inclusions into single chain polymer nanoparticles, while concurrently promoting intramolecular collapse.

Original languageEnglish (US)
Pages (from-to)3765-3773
Number of pages9
JournalPolymer Chemistry
Volume4
Issue number13
DOIs
StatePublished - Jul 7 2013

Fingerprint

Atom transfer radical polymerization
Polymerization
Nanoparticles
Polymers
Crosslinking
poly(3,4-propylenedioxythiophene)

ASJC Scopus subject areas

  • Polymers and Plastics
  • Organic Chemistry
  • Biochemistry
  • Biomedical Engineering
  • Bioengineering

Cite this

Dirlam, P. T., Kim, H. J., Arrington, K. J., Chung, W. J., Sahoo, R., Hill, L. J., ... Pyun, D-C. (2013). Single chain polymer nanoparticles via sequential ATRP and oxidative polymerization. Polymer Chemistry, 4(13), 3765-3773. https://doi.org/10.1039/c3py00321c

Single chain polymer nanoparticles via sequential ATRP and oxidative polymerization. / Dirlam, Philip T.; Kim, Hyo Ju; Arrington, Kyle J.; Chung, Woo Jin; Sahoo, Rabindra; Hill, Lawrence J.; Costanzo, Philip J.; Theato, Patrick; Char, Kookheon; Pyun, Dong-Chul.

In: Polymer Chemistry, Vol. 4, No. 13, 07.07.2013, p. 3765-3773.

Research output: Contribution to journalArticle

Dirlam, PT, Kim, HJ, Arrington, KJ, Chung, WJ, Sahoo, R, Hill, LJ, Costanzo, PJ, Theato, P, Char, K & Pyun, D-C 2013, 'Single chain polymer nanoparticles via sequential ATRP and oxidative polymerization', Polymer Chemistry, vol. 4, no. 13, pp. 3765-3773. https://doi.org/10.1039/c3py00321c
Dirlam PT, Kim HJ, Arrington KJ, Chung WJ, Sahoo R, Hill LJ et al. Single chain polymer nanoparticles via sequential ATRP and oxidative polymerization. Polymer Chemistry. 2013 Jul 7;4(13):3765-3773. https://doi.org/10.1039/c3py00321c
Dirlam, Philip T. ; Kim, Hyo Ju ; Arrington, Kyle J. ; Chung, Woo Jin ; Sahoo, Rabindra ; Hill, Lawrence J. ; Costanzo, Philip J. ; Theato, Patrick ; Char, Kookheon ; Pyun, Dong-Chul. / Single chain polymer nanoparticles via sequential ATRP and oxidative polymerization. In: Polymer Chemistry. 2013 ; Vol. 4, No. 13. pp. 3765-3773.
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