Single chain polymer nanoparticles via sequential ATRP and oxidative polymerization

Philip T. Dirlam, Hyo Ju Kim, Kyle J. Arrington, Woo Jin Chung, Rabindra Sahoo, Lawrence J. Hill, Philip J. Costanzo, Patrick Theato, Kookheon Char, Jeffrey Pyun

Research output: Contribution to journalArticle

34 Scopus citations

Abstract

The synthesis of single chain nanoparticles has been achieved by the synthesis of a linear polystyrenic precursor carrying 3,4- propylenedioxythiophene groups via atom transfer radical polymerization followed by intramolecular crosslinking via oxidative polymerization. This methodology enabled the introduction of electroactive inclusions into single chain polymer nanoparticles, while concurrently promoting intramolecular collapse.

Original languageEnglish (US)
Pages (from-to)3765-3773
Number of pages9
JournalPolymer Chemistry
Volume4
Issue number13
DOIs
StatePublished - Jul 7 2013

ASJC Scopus subject areas

  • Bioengineering
  • Biochemistry
  • Polymers and Plastics
  • Organic Chemistry

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  • Cite this

    Dirlam, P. T., Kim, H. J., Arrington, K. J., Chung, W. J., Sahoo, R., Hill, L. J., Costanzo, P. J., Theato, P., Char, K., & Pyun, J. (2013). Single chain polymer nanoparticles via sequential ATRP and oxidative polymerization. Polymer Chemistry, 4(13), 3765-3773. https://doi.org/10.1039/c3py00321c