Single reactor route to polar superlattices. Layer-by-layer self-assembly of large-response molecular electrooptic materials by protection-deprotection

M. E. Van der Boom, A. G. Richter, J. E. Malinsky, P. A. Lee, Neal R Armstrong, P. Dutta, T. J. Marks

Research output: Contribution to journalArticle

50 Citations (Scopus)

Abstract

Protection-deprotection of silyl-derivatized surface hydroxyl groups represents a new, "one-pot" strategy for the layer-by-layer construction of polar, covalently interlinked electrooptic molecular superlattices. These, siloxane-based multilayer structures are shown to be smooth, adherent, and structurally regular and to exhibit excellent electrooptic/nonlinear optic responses with χ(2) zzz∼220 pm/V and r33∼80 pm/V without electric field poling. This all "wet-chemical self-assembly approach should be readily amenable to automation.

Original languageEnglish (US)
Pages (from-to)15-17
Number of pages3
JournalChemistry of Materials
Volume13
Issue number1
DOIs
StatePublished - 2001

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Superlattices
Electrooptical effects
Self assembly
Siloxanes
Nonlinear optics
Hydroxyl Radical
Multilayers
Automation
Electric fields

ASJC Scopus subject areas

  • Materials Chemistry
  • Materials Science(all)

Cite this

Single reactor route to polar superlattices. Layer-by-layer self-assembly of large-response molecular electrooptic materials by protection-deprotection. / Van der Boom, M. E.; Richter, A. G.; Malinsky, J. E.; Lee, P. A.; Armstrong, Neal R; Dutta, P.; Marks, T. J.

In: Chemistry of Materials, Vol. 13, No. 1, 2001, p. 15-17.

Research output: Contribution to journalArticle

Van der Boom, M. E. ; Richter, A. G. ; Malinsky, J. E. ; Lee, P. A. ; Armstrong, Neal R ; Dutta, P. ; Marks, T. J. / Single reactor route to polar superlattices. Layer-by-layer self-assembly of large-response molecular electrooptic materials by protection-deprotection. In: Chemistry of Materials. 2001 ; Vol. 13, No. 1. pp. 15-17.
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