Size-resolved composition and morphology of particulate matter during the southwest monsoon in Metro Manila, Philippines

Melliza Templonuevo Cruz, Paola Angela Bañaga, Paola Angela Bañaga, Grace Betito, Rachel A. Braun, Connor Stahl, Mojtaba Azadi Aghdam, Maria Obiminda Cambaliza, Hossein Dadashazar, Miguel Ricardo Hilario, Genevieve Rose Lorenzo, Lin Ma, Alexander B. MacDonald, Preciosa Corazon Pabroa, John Robin Yee, James Bernard Simpas, Armin Sorooshian

Research output: Contribution to journalArticle

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Abstract

This paper presents novel results from sizeresolved particulate matter (PM) mass, composition, and morphology measurements conducted during the 2018 southwest monsoon (SWM) season in Metro Manila, Philippines. Micro-orifice uniform deposit impactors (MOUDIs) were used to collect PM sample sets composed of sizeresolved measurements at the following aerodynamic cutpoint diameters (Dp): 18, 10, 5.6, 3.2, 1.8, 1.0, 0.56, 0.32, 0.18, 0.10, and 0.056 μm. Each sample set was analyzed for composition of the water-soluble fraction. Analysis for mass was carried out on two sample sets, whereas black carbon (BC) and morphology analysis were analyzed on a single sample set. The bulk of the PM mass was between 0.18 and 1.0 μm with a dominant mode between 0.32 and 0.56 μm. Similarly, most of the black carbon (BC) mass was found between 0.10 and 1.0 μm, peaking between 0.18 and 0.32 μm. These peaks are located in the Greenfield gap, or the size range between 0.10 and 1.0 μm, where wet scavenging by rain is relatively inefficient. In the range between 0.10 and 0.18 μm, BC constituted 78.1 % of the measured mass. Comparable contributions of BC (26.9 %) and the water-soluble fraction (33.4 %) to total PM were observed and most of the unresolved mass, which amounted to 39.6 % in total, was for diameters exceeding 0.32 μm. The water-soluble ions and elements exhibited an average combined concentration of 8.53 μg m-3, with SO24-, NHC4, NO-3, NaC, and Cl-as the major contributors. Positive matrix factorization (PMF) was applied to identify the possible aerosol sources and estimate their contribution to the water-soluble fraction of collected PM. The factor with the highest contribution was attributed to "aged aerosol" (48.0 %), while "sea salt" (22.5 %) and "combustion" emissions (18.7 %) had comparable contributions. "Vehicular/resuspended dust" (5.6 %) and "waste processing" emissions (5.1 %) were also identified. Microscopy analysis highlighted the ubiquity of nonspherical particles regardless of size, which is significant when considering calculations of parameters such as single scattering albedo, the asymmetry parameter, and the extinction efficiency. The significant influence from aged aerosol to Metro Manila during the SWM season indicates that local sources in this megacity do not fully govern this coastal area's aerosol properties. The fact that the majority of the regional aerosol mass burden is accounted for by BC and other insoluble components has important downstream effects on the aerosol hygroscopic properties, which depend on composition. The results are relevant for understanding the impacts of monsoonal features on size-resolved aerosol properties, notably aqueous processing and wet scavenging. Finally, the results of this work provide contextual data for future sampling campaigns in Southeast Asia such as the airborne component of the Cloud, Aerosol, and Monsoon Processes Philippines Experiment (CAMP2Ex) planned for the SWM season in 2019.

Original languageEnglish (US)
Pages (from-to)10675-10696
Number of pages22
JournalAtmospheric Chemistry and Physics
Volume19
Issue number16
DOIs
StatePublished - Aug 23 2019

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particulate matter
monsoon
black carbon
aerosol property
aerosol
water
megacity
volcanic cloud
sea salt
range size
aerodynamics
albedo
microscopy
asymmetry
combustion
extinction
scattering
dust
matrix
ion

ASJC Scopus subject areas

  • Atmospheric Science

Cite this

Size-resolved composition and morphology of particulate matter during the southwest monsoon in Metro Manila, Philippines. / Cruz, Melliza Templonuevo; Bañaga, Paola Angela; Bañaga, Paola Angela; Betito, Grace; Braun, Rachel A.; Stahl, Connor; Aghdam, Mojtaba Azadi; Obiminda Cambaliza, Maria; Dadashazar, Hossein; Hilario, Miguel Ricardo; Lorenzo, Genevieve Rose; Ma, Lin; MacDonald, Alexander B.; Pabroa, Preciosa Corazon; Yee, John Robin; Simpas, James Bernard; Sorooshian, Armin.

In: Atmospheric Chemistry and Physics, Vol. 19, No. 16, 23.08.2019, p. 10675-10696.

Research output: Contribution to journalArticle

Cruz, MT, Bañaga, PA, Bañaga, PA, Betito, G, Braun, RA, Stahl, C, Aghdam, MA, Obiminda Cambaliza, M, Dadashazar, H, Hilario, MR, Lorenzo, GR, Ma, L, MacDonald, AB, Pabroa, PC, Yee, JR, Simpas, JB & Sorooshian, A 2019, 'Size-resolved composition and morphology of particulate matter during the southwest monsoon in Metro Manila, Philippines', Atmospheric Chemistry and Physics, vol. 19, no. 16, pp. 10675-10696. https://doi.org/10.5194/acp-19-10675-2019
Cruz, Melliza Templonuevo ; Bañaga, Paola Angela ; Bañaga, Paola Angela ; Betito, Grace ; Braun, Rachel A. ; Stahl, Connor ; Aghdam, Mojtaba Azadi ; Obiminda Cambaliza, Maria ; Dadashazar, Hossein ; Hilario, Miguel Ricardo ; Lorenzo, Genevieve Rose ; Ma, Lin ; MacDonald, Alexander B. ; Pabroa, Preciosa Corazon ; Yee, John Robin ; Simpas, James Bernard ; Sorooshian, Armin. / Size-resolved composition and morphology of particulate matter during the southwest monsoon in Metro Manila, Philippines. In: Atmospheric Chemistry and Physics. 2019 ; Vol. 19, No. 16. pp. 10675-10696.
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T1 - Size-resolved composition and morphology of particulate matter during the southwest monsoon in Metro Manila, Philippines

AU - Cruz, Melliza Templonuevo

AU - Bañaga, Paola Angela

AU - Bañaga, Paola Angela

AU - Betito, Grace

AU - Braun, Rachel A.

AU - Stahl, Connor

AU - Aghdam, Mojtaba Azadi

AU - Obiminda Cambaliza, Maria

AU - Dadashazar, Hossein

AU - Hilario, Miguel Ricardo

AU - Lorenzo, Genevieve Rose

AU - Ma, Lin

AU - MacDonald, Alexander B.

AU - Pabroa, Preciosa Corazon

AU - Yee, John Robin

AU - Simpas, James Bernard

AU - Sorooshian, Armin

PY - 2019/8/23

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N2 - This paper presents novel results from sizeresolved particulate matter (PM) mass, composition, and morphology measurements conducted during the 2018 southwest monsoon (SWM) season in Metro Manila, Philippines. Micro-orifice uniform deposit impactors (MOUDIs) were used to collect PM sample sets composed of sizeresolved measurements at the following aerodynamic cutpoint diameters (Dp): 18, 10, 5.6, 3.2, 1.8, 1.0, 0.56, 0.32, 0.18, 0.10, and 0.056 μm. Each sample set was analyzed for composition of the water-soluble fraction. Analysis for mass was carried out on two sample sets, whereas black carbon (BC) and morphology analysis were analyzed on a single sample set. The bulk of the PM mass was between 0.18 and 1.0 μm with a dominant mode between 0.32 and 0.56 μm. Similarly, most of the black carbon (BC) mass was found between 0.10 and 1.0 μm, peaking between 0.18 and 0.32 μm. These peaks are located in the Greenfield gap, or the size range between 0.10 and 1.0 μm, where wet scavenging by rain is relatively inefficient. In the range between 0.10 and 0.18 μm, BC constituted 78.1 % of the measured mass. Comparable contributions of BC (26.9 %) and the water-soluble fraction (33.4 %) to total PM were observed and most of the unresolved mass, which amounted to 39.6 % in total, was for diameters exceeding 0.32 μm. The water-soluble ions and elements exhibited an average combined concentration of 8.53 μg m-3, with SO24-, NHC4, NO-3, NaC, and Cl-as the major contributors. Positive matrix factorization (PMF) was applied to identify the possible aerosol sources and estimate their contribution to the water-soluble fraction of collected PM. The factor with the highest contribution was attributed to "aged aerosol" (48.0 %), while "sea salt" (22.5 %) and "combustion" emissions (18.7 %) had comparable contributions. "Vehicular/resuspended dust" (5.6 %) and "waste processing" emissions (5.1 %) were also identified. Microscopy analysis highlighted the ubiquity of nonspherical particles regardless of size, which is significant when considering calculations of parameters such as single scattering albedo, the asymmetry parameter, and the extinction efficiency. The significant influence from aged aerosol to Metro Manila during the SWM season indicates that local sources in this megacity do not fully govern this coastal area's aerosol properties. The fact that the majority of the regional aerosol mass burden is accounted for by BC and other insoluble components has important downstream effects on the aerosol hygroscopic properties, which depend on composition. The results are relevant for understanding the impacts of monsoonal features on size-resolved aerosol properties, notably aqueous processing and wet scavenging. Finally, the results of this work provide contextual data for future sampling campaigns in Southeast Asia such as the airborne component of the Cloud, Aerosol, and Monsoon Processes Philippines Experiment (CAMP2Ex) planned for the SWM season in 2019.

AB - This paper presents novel results from sizeresolved particulate matter (PM) mass, composition, and morphology measurements conducted during the 2018 southwest monsoon (SWM) season in Metro Manila, Philippines. Micro-orifice uniform deposit impactors (MOUDIs) were used to collect PM sample sets composed of sizeresolved measurements at the following aerodynamic cutpoint diameters (Dp): 18, 10, 5.6, 3.2, 1.8, 1.0, 0.56, 0.32, 0.18, 0.10, and 0.056 μm. Each sample set was analyzed for composition of the water-soluble fraction. Analysis for mass was carried out on two sample sets, whereas black carbon (BC) and morphology analysis were analyzed on a single sample set. The bulk of the PM mass was between 0.18 and 1.0 μm with a dominant mode between 0.32 and 0.56 μm. Similarly, most of the black carbon (BC) mass was found between 0.10 and 1.0 μm, peaking between 0.18 and 0.32 μm. These peaks are located in the Greenfield gap, or the size range between 0.10 and 1.0 μm, where wet scavenging by rain is relatively inefficient. In the range between 0.10 and 0.18 μm, BC constituted 78.1 % of the measured mass. Comparable contributions of BC (26.9 %) and the water-soluble fraction (33.4 %) to total PM were observed and most of the unresolved mass, which amounted to 39.6 % in total, was for diameters exceeding 0.32 μm. The water-soluble ions and elements exhibited an average combined concentration of 8.53 μg m-3, with SO24-, NHC4, NO-3, NaC, and Cl-as the major contributors. Positive matrix factorization (PMF) was applied to identify the possible aerosol sources and estimate their contribution to the water-soluble fraction of collected PM. The factor with the highest contribution was attributed to "aged aerosol" (48.0 %), while "sea salt" (22.5 %) and "combustion" emissions (18.7 %) had comparable contributions. "Vehicular/resuspended dust" (5.6 %) and "waste processing" emissions (5.1 %) were also identified. Microscopy analysis highlighted the ubiquity of nonspherical particles regardless of size, which is significant when considering calculations of parameters such as single scattering albedo, the asymmetry parameter, and the extinction efficiency. The significant influence from aged aerosol to Metro Manila during the SWM season indicates that local sources in this megacity do not fully govern this coastal area's aerosol properties. The fact that the majority of the regional aerosol mass burden is accounted for by BC and other insoluble components has important downstream effects on the aerosol hygroscopic properties, which depend on composition. The results are relevant for understanding the impacts of monsoonal features on size-resolved aerosol properties, notably aqueous processing and wet scavenging. Finally, the results of this work provide contextual data for future sampling campaigns in Southeast Asia such as the airborne component of the Cloud, Aerosol, and Monsoon Processes Philippines Experiment (CAMP2Ex) planned for the SWM season in 2019.

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