Sodalite-like rare-earth carbonates: A study of structural transformation and diluted magnetism

Yanyan Wang, Tian Han, You Song Ding, Zhiping Zheng, Yan Zhen Zheng

Research output: Contribution to journalArticle

4 Scopus citations

Abstract

A series of novel rare earth carbonates, RE3(OH)6(CO3)Cl (RE = Dy, Er, Y), with sodalite-like (SOD-like) zeolite topologies have been successfully synthesized by introducing an appropriate amount of CO3 2- from NaCO3 or atmospheric carbon dioxide as a template. Single-crystal X-ray diffraction reveals that the structure consists of the RE3(OH)6 3+ cationic framework with a SOD-like topology built from vertex-sharing [RE43-OH)4] cubes. The CO3 2- anions seal the 6-ring opening and Cl- anions situated in the channels to achieve charge balance. After calcination at 370°C, the compound RE3(OH)6(CO3)Cl in situ transforms into a new phase formulated as RE3O4Cl. Interestingly, the structure of RE3O4Cl represents a new SOD-like open framework, associated with the removal of the CO3 2- from RE3(OH)6(CO3)Cl. The samples are characterized by thermogravimetric analysis (TGA), elemental analysis, X-ray photoelectron spectroscopy and magnetic studies. Furthermore, single-molecule magnet behaviours can be observed for the diluted samples of Dy0.0068Y2.9932(OH)6(CO3)Cl and Dy0.0068Y2.9932O4Cl with a Dy/Y molar ratio of up to 1/440 as well as Er0.19Y2.81(OH)6(CO3)Cl with an Er/Y ratio of 1/15, showing dominant single-ion effects.

Original languageEnglish (US)
Pages (from-to)1103-1110
Number of pages8
JournalDalton Transactions
Volume45
Issue number3
DOIs
StatePublished - 2016

ASJC Scopus subject areas

  • Inorganic Chemistry

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