Abstract
Phosphorane ylides and phosphonate anions react smoothly with resin-bound aldehydes and ketones to provide alkenes in good yields and purities (assessed after cleavage of acid-labile PAL anchor to support). The reactions of aldehydes give excellent stereoselectivities. Effective conditions have been developed for carrying out these transformations.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 1697-1702 |
| Number of pages | 6 |
| Journal | Collection of Czechoslovak Chemical Communications |
| Volume | 61 |
| Issue number | 12 |
| DOIs | |
| State | Published - Dec 1996 |
| Externally published | Yes |
Keywords
- Combinatorial chemistry
- Solid-phase synthesis
- Wittig reaction
ASJC Scopus subject areas
- Chemistry(all)
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Vágner, J., Krchňák, V., Lebl, M., & Barany, G. (1996). Solid-phase organic synthesis: Creation of carbon-carbon double bonds under mild conditions by Wittig-type reactions. Collection of Czechoslovak Chemical Communications, 61(12), 1697-1702. https://doi.org/10.1135/cccc19961697