Solute redistribution during crystallization at constant velocity and constant temperature

R. W. Hopper, Donald R Uhlmann

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

An analysis is presented for the time-dependent solute redistribution which occurs during crystallization at constant velocity and constant temperature. The analysis is suggested to be applicable to many studies of crystallization in glass-forming systems, where solidification takes place at temperatures well above the solidus and where the solubility in the crystalline phase is quite limited. Appropriate for these situations, the usual condition of Cs = kCL is replaced by the approximate condition of Cs = Csolidus. The results indicate a concentration of the liquid at the interface which is limited only by the liquidus composition, and not by a steady-state composition of CO/k. Limitations of the present analysis for cases where the growth rate becomes concentration-dependent are discussed.

Original languageEnglish (US)
Pages (from-to)203-213
Number of pages11
JournalJournal of Crystal Growth
Volume21
Issue number2
DOIs
StatePublished - 1974
Externally publishedYes

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Crystallization
solutes
crystallization
solidus
liquidus
Carbon Monoxide
Chemical analysis
solidification
Solidification
solubility
Solubility
Crystalline materials
Glass
Temperature
temperature
glass
Liquids
liquids

ASJC Scopus subject areas

  • Condensed Matter Physics

Cite this

Solute redistribution during crystallization at constant velocity and constant temperature. / Hopper, R. W.; Uhlmann, Donald R.

In: Journal of Crystal Growth, Vol. 21, No. 2, 1974, p. 203-213.

Research output: Contribution to journalArticle

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