Solvent extraction of copper by Cyanex 272, Cyanex 302 and Cyanex 301

Kathryn C. Sole, J Brent Hiskey

Research output: Contribution to journalArticle

129 Citations (Scopus)

Abstract

The mechanisms of copper(II) solvent extraction by Cyanex 272, Cyanex 302 and Cyanex 301 are discussed. Extraction from sulfate media is strongly dependant upon sulfur substitution in the phosphinic acid and complete extraction of copper by Cyanex 302 and Cyanex 301 occurs below pH 0. Since conventional slope analysis is not possible under these conditions, the complex stoichiometries and geometries are inferred from analysis of the electronic, 31P-NMR and FAB-MS spectra of the complexed species. Cu(II) is reduced to Cu(I) on extraction by the sulfur-containing ligands, accompanied by the corresponding oxidation of the extractant. It is shown that copper combines in a 1:1 stoichiometric ratio with these ligands to form multinuclear oligomeric complexes, in which the ligands bridge between metal centers. The enhanced stabilities of the complexes formed with the sulfur-containing ligands are explained in terms of the Hard-Soft Acid-Base concept and pi bonding between the d orbitals of the metal center and the donor atoms.

Original languageEnglish (US)
Pages (from-to)129-147
Number of pages19
JournalHydrometallurgy
Volume37
Issue number2
DOIs
StatePublished - 1995

Fingerprint

Solvent extraction
ligand
Copper
Ligands
Sulfur
copper
sulfur
Phosphinic Acids
Metals
Acids
acid
metal
stoichiometry
Stoichiometry
Sulfates
nuclear magnetic resonance
substitution
Substitution reactions
Nuclear magnetic resonance
sulfate

ASJC Scopus subject areas

  • Industrial and Manufacturing Engineering
  • Materials Chemistry
  • Metals and Alloys
  • Geochemistry and Petrology
  • Geotechnical Engineering and Engineering Geology

Cite this

Solvent extraction of copper by Cyanex 272, Cyanex 302 and Cyanex 301. / Sole, Kathryn C.; Hiskey, J Brent.

In: Hydrometallurgy, Vol. 37, No. 2, 1995, p. 129-147.

Research output: Contribution to journalArticle

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AB - The mechanisms of copper(II) solvent extraction by Cyanex 272, Cyanex 302 and Cyanex 301 are discussed. Extraction from sulfate media is strongly dependant upon sulfur substitution in the phosphinic acid and complete extraction of copper by Cyanex 302 and Cyanex 301 occurs below pH 0. Since conventional slope analysis is not possible under these conditions, the complex stoichiometries and geometries are inferred from analysis of the electronic, 31P-NMR and FAB-MS spectra of the complexed species. Cu(II) is reduced to Cu(I) on extraction by the sulfur-containing ligands, accompanied by the corresponding oxidation of the extractant. It is shown that copper combines in a 1:1 stoichiometric ratio with these ligands to form multinuclear oligomeric complexes, in which the ligands bridge between metal centers. The enhanced stabilities of the complexes formed with the sulfur-containing ligands are explained in terms of the Hard-Soft Acid-Base concept and pi bonding between the d orbitals of the metal center and the donor atoms.

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