Spectroscopic, theoretical, and electrochemical studies of 1,2-dithiins

Richard S. Glass, John R. Pollard, T. Benjamin Schroeder, Dennis L. Lichtenberger, Eric Block, Russell DeOrazio, Chuangxing Guo, Mohan Thiruvazhi

Research output: Contribution to journalArticle

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Abstract

The lowest oxidation potentials for 1,2-dithiins are in the range of 0.67-0.96 V in acetonitrile and 0.81-1.04 V in dichloromethane. These oxidation potentials are less anodic than expected based on the ionization potentials of 1,2-dithiin determined by photoelectron spectroscopy. Theoretical calculations suggest that the reason for this difference is a change in optimized geometry between 1,2-dithiin and its oxidized species.

Original languageEnglish (US)
Pages (from-to)439-440
Number of pages2
JournalPhosphorus, Sulfur and Silicon and Related Elements
Volume120-121
DOIs
StatePublished - Jan 1 1997

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ASJC Scopus subject areas

  • Biochemistry
  • Organic Chemistry
  • Inorganic Chemistry

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