Spectroscopic, theoretical, and electrochemical studies of 1,2-dithiins

Richard S. Glass; John R. Pollard; T. Benjamin Schroeder; Dennis L. Lichtenberger; Eric Block; Russell DeOrazio; Chuangxing Guo; Mohan Thiruvazhi

doi:10.1080/10426509708545587

Spectroscopic, theoretical, and electrochemical studies of 1,2-dithiins

Richard S. Glass, John R. Pollard, T. Benjamin Schroeder, Dennis L. Lichtenberger, Eric Block, Russell DeOrazio, Chuangxing Guo, Mohan Thiruvazhi

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The lowest oxidation potentials for 1,2-dithiins are in the range of 0.67-0.96 V in acetonitrile and 0.81-1.04 V in dichloromethane. These oxidation potentials are less anodic than expected based on the ionization potentials of 1,2-dithiin determined by photoelectron spectroscopy. Theoretical calculations suggest that the reason for this difference is a change in optimized geometry between 1,2-dithiin and its oxidized species.

Original language	English (US)
Pages (from-to)	439-440
Number of pages	2
Journal	Phosphorus, Sulfur and Silicon and Related Elements
Volume	120-121
DOIs	https://doi.org/10.1080/10426509708545587
State	Published - Jan 1 1997

ASJC Scopus subject areas

Biochemistry
Organic Chemistry
Inorganic Chemistry

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Spectroscopic, theoretical, and electrochemical studies of 1,2-dithiins. / Glass, Richard S.; Pollard, John R.; Schroeder, T. Benjamin; Lichtenberger, Dennis L.; Block, Eric; DeOrazio, Russell; Guo, Chuangxing; Thiruvazhi, Mohan.

In: Phosphorus, Sulfur and Silicon and Related Elements, Vol. 120-121, 01.01.1997, p. 439-440.

Research output: Contribution to journal › Article › peer-review

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AU - DeOrazio, Russell

AU - Guo, Chuangxing

AU - Thiruvazhi, Mohan

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