Starting materials and superconductor stoichiometry

C. E. Hamrin, W David Arnett, R. J. De Angelis, X. X. Ding, W. D. Ehmann

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Oxygen contents of as-received La2O3 and Nd2O3 were determined by fast neutron activation analysis. X-ray diffraction was used to determine the phases present in these materials. Results of these analyses show that significant amounts of hydroxides (in one case over 90 wt%) were present in all oxide samples. These results carry tremendous implications for the stoichiometry of the superconductor formation reaction and the composition of the final product. The most important conclusion to be drawn from this study is that many of the bulk superconducting ceramics produced to date may be of approximate composition at best.

Original languageEnglish (US)
Pages (from-to)1063-1066
Number of pages4
JournalSolid State Communications
Volume69
Issue number11
DOIs
StatePublished - 1989
Externally publishedYes

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Stoichiometry
Superconducting materials
stoichiometry
Hydroxides
neutron activation analysis
Neutron activation analysis
fast neutrons
Chemical analysis
Oxides
hydroxides
ceramics
Oxygen
X ray diffraction
oxides
oxygen
products
diffraction
x rays
neodymium oxide

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Hamrin, C. E., Arnett, W. D., De Angelis, R. J., Ding, X. X., & Ehmann, W. D. (1989). Starting materials and superconductor stoichiometry. Solid State Communications, 69(11), 1063-1066. https://doi.org/10.1016/0038-1098(89)90487-0

Starting materials and superconductor stoichiometry. / Hamrin, C. E.; Arnett, W David; De Angelis, R. J.; Ding, X. X.; Ehmann, W. D.

In: Solid State Communications, Vol. 69, No. 11, 1989, p. 1063-1066.

Research output: Contribution to journalArticle

Hamrin, CE, Arnett, WD, De Angelis, RJ, Ding, XX & Ehmann, WD 1989, 'Starting materials and superconductor stoichiometry', Solid State Communications, vol. 69, no. 11, pp. 1063-1066. https://doi.org/10.1016/0038-1098(89)90487-0
Hamrin, C. E. ; Arnett, W David ; De Angelis, R. J. ; Ding, X. X. ; Ehmann, W. D. / Starting materials and superconductor stoichiometry. In: Solid State Communications. 1989 ; Vol. 69, No. 11. pp. 1063-1066.
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