Structure of an enantiomerically pure tetrahydropyranyl ether

Eugene A Mash, James A. Fryling, Pamela A. Wexler

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

(2S)-Methyl 2-phenyl-2-[(2S)tetrahydro-2(2H)-pyranyloxy]acetate, C 14H18O4, Mr = 250.29, orthorhombic, P212121, a = 7.850(1), b = 8.211(1), c = 21.123 (3) Å, V= 1361.5 (3) Å3, Z = 4, Dx = 1.22 g cm-3, Mo Kα, λ = 0.71073 Å, μ=0.8 cm -1, F(000) = 536, T=296K, R = 0.039 for 973 unique reflections with Fo2 > 3σ(Fo2). In this diastereomer the anomeric alkoxy substituent is axially oriented. The absolute stereochemistry at the anomeric carbon is assigned as S based upon the known stereochemistry of the mandelate ester.

Original languageEnglish (US)
Pages (from-to)2708-2709
Number of pages2
JournalActa Crystallographica Section C: Crystal Structure Communications
Volume47
Issue number12
DOIs
StatePublished - 1991

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Stereochemistry
Ether
Esters
Acetates
Carbon
alkoxyl radical

ASJC Scopus subject areas

  • Biochemistry, Genetics and Molecular Biology(all)

Cite this

Structure of an enantiomerically pure tetrahydropyranyl ether. / Mash, Eugene A; Fryling, James A.; Wexler, Pamela A.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. 47, No. 12, 1991, p. 2708-2709.

Research output: Contribution to journalArticle

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