Study of the role of heterogeneities in the initial stages of corrosion of glazes using dynamic imaging microellipsometry (DIM)

B. E. McCarthy, Pamela B Vandiver, J. Kruger

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Common processes used in glazed ceramic production often result in a glaze with a heterogeneous microstructure. Heterogeneities may he due to residual batch materials, intentionally added colorants and opacifiers and/or the products of devitrification and phase separation. To study the effect of heterogeneities in the corrosion process, dynamic imaging microellipsometry was used in-situ in aqueous solutions to measure spatially and temporally resolved changes in the surface of glasses (model glazes). The measurements showed increased durability near inclusions. Residual stress fields surrounding the heterogeneities influenced the results. Decoupling of chemical and mechanical factors causing this increased durability was not possible.

Original languageEnglish (US)
Title of host publicationMaterials Research Society Symposium - Proceedings
EditorsP.B. Vandiver, J.R. Druzik, J.F. Merkel, J. Stewart
PublisherMRS
Pages31-38
Number of pages8
Volume462
StatePublished - 1997
Externally publishedYes
EventProceedings of the 1996 MRS Fall Symposium - Boston, MA, USA
Duration: Dec 3 1996Dec 5 1996

Other

OtherProceedings of the 1996 MRS Fall Symposium
CityBoston, MA, USA
Period12/3/9612/5/96

Fingerprint

Glazes
Opacifiers
Durability
Corrosion
Imaging techniques
Phase separation
Residual stresses
Glass
Microstructure

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials

Cite this

McCarthy, B. E., Vandiver, P. B., & Kruger, J. (1997). Study of the role of heterogeneities in the initial stages of corrosion of glazes using dynamic imaging microellipsometry (DIM). In P. B. Vandiver, J. R. Druzik, J. F. Merkel, & J. Stewart (Eds.), Materials Research Society Symposium - Proceedings (Vol. 462, pp. 31-38). MRS.

Study of the role of heterogeneities in the initial stages of corrosion of glazes using dynamic imaging microellipsometry (DIM). / McCarthy, B. E.; Vandiver, Pamela B; Kruger, J.

Materials Research Society Symposium - Proceedings. ed. / P.B. Vandiver; J.R. Druzik; J.F. Merkel; J. Stewart. Vol. 462 MRS, 1997. p. 31-38.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

McCarthy, BE, Vandiver, PB & Kruger, J 1997, Study of the role of heterogeneities in the initial stages of corrosion of glazes using dynamic imaging microellipsometry (DIM). in PB Vandiver, JR Druzik, JF Merkel & J Stewart (eds), Materials Research Society Symposium - Proceedings. vol. 462, MRS, pp. 31-38, Proceedings of the 1996 MRS Fall Symposium, Boston, MA, USA, 12/3/96.
McCarthy BE, Vandiver PB, Kruger J. Study of the role of heterogeneities in the initial stages of corrosion of glazes using dynamic imaging microellipsometry (DIM). In Vandiver PB, Druzik JR, Merkel JF, Stewart J, editors, Materials Research Society Symposium - Proceedings. Vol. 462. MRS. 1997. p. 31-38
McCarthy, B. E. ; Vandiver, Pamela B ; Kruger, J. / Study of the role of heterogeneities in the initial stages of corrosion of glazes using dynamic imaging microellipsometry (DIM). Materials Research Society Symposium - Proceedings. editor / P.B. Vandiver ; J.R. Druzik ; J.F. Merkel ; J. Stewart. Vol. 462 MRS, 1997. pp. 31-38
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