Sub-millimeter spectroscopy of BaS (X1Σ+)

A. Janczyk, L. M. Ziurys

Research output: Contribution to journalArticle

4 Scopus citations

Abstract

The pure rotational spectrum of BaS (X1Σ+) has been recorded in the frequency range 355-396 GHz using direct absorption methods. Data were recorded for six isotopomers: 138Ba32S, 137Ba32S, 136B32S, 135Ba32S, 134Ba32S, and 138Ba34S, in vibrational states ranging from v = 0 to v = 6. This work is an extension of past microwave and millimeter studies. Revised spectroscopic constants have been established for the six species. The dissociation energy for 138Ba32S is estimated to be DEhc∼ 42 392 cm-1.

Original languageEnglish (US)
Pages (from-to)11-15
Number of pages5
JournalJournal of Molecular Spectroscopy
Volume236
Issue number1
DOIs
StatePublished - Mar 1 2006

Keywords

  • Bond lengths
  • Diatomics
  • Dissociation energy
  • Rotational parameters
  • Rotational spectra
  • Sub-mm/THz

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

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