Subliquidus Immiscibility in Binary Alkali Borates

R. R. SHAW, Donald R Uhlmann

Research output: Contribution to journalArticle

87 Citations (Scopus)

Abstract

The phase boundaries of subliquidus immiscibility in the lithium, sodium, potassium, rubidium, and cesium borate systems were determined. Two‐phase structures were developed in thermal gradients and examined by direct‐transmission electron microscopy. No opalescence was observed. Microstructures were of the order of a few hundred angstroms. The extent of immiscibility in each system was determined by the approximate intersection of the immiscible phase boundary with the glass transition region.

Original languageEnglish (US)
Pages (from-to)377-382
Number of pages6
JournalJournal of the American Ceramic Society
Volume51
Issue number7
DOIs
StatePublished - 1968
Externally publishedYes

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Borates
Alkalies
Phase boundaries
Solubility
Rubidium
Cesium
Lithium
Thermal gradients
Electron microscopy
Potassium
Glass transition
Sodium
Microstructure

ASJC Scopus subject areas

  • Ceramics and Composites
  • Materials Chemistry

Cite this

Subliquidus Immiscibility in Binary Alkali Borates. / SHAW, R. R.; Uhlmann, Donald R.

In: Journal of the American Ceramic Society, Vol. 51, No. 7, 1968, p. 377-382.

Research output: Contribution to journalArticle

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