Synthesis and Electrooptic Properties of a New Chromophore Dispersed or Grafted in a Carbazolyl Methacrylate Matrix

C. Maertens; C. Detrembleur; P. Dubois; R. Jérôme; P. A. Blanche; Ph C. Lemaire

doi:10.1021/cm970472l

Synthesis and Electrooptic Properties of a New Chromophore Dispersed or Grafted in a Carbazolyl Methacrylate Matrix

C. Maertens, C. Detrembleur, P. Dubois, R. Jérôme, P. A. Blanche, Ph C. Lemaire

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A copolymer of [11-(N-carbazolyl)undecyl methacrylate] and ethyl (E)-2-cyano-3[5-(5-(4-methacryloyloxy)piperidino-2-thienylcarbonyl)-2-thienyl]- 2-propenoate has been prepared. The photoconductivity and the electrooptic properties of a hot-pressed thin film of this copolymer have been measured and compared with the properties of the dispersion of ethyl (E)-2-cyano-3[5-(5-piperidino-2-thienylcarbonyl)-2-thienyl]-2-propenoate within a poly[11-(N-carbazolyl)undecyl methacrylate] matrix. The electrooptic coefficient has been measured by both interferometric and polarimetric techniques. The interferometric technique was not appropriated because the strong electric field applied to the electrodes changes the film thickness of these low T_g materials. A value of up to 5 pm/V for the figure of merit n³(r₁₃ - r₃₃) has been reported for the dispersed material, which is 10 times higher than the corresponding grafted material, and a linear relationship between the poling intensity and the electrooptic coefficient has been observed for the two materials.

Original language	English (US)
Pages (from-to)	1010-1016
Number of pages	7
Journal	Chemistry of Materials
Volume	10
Issue number	4
DOIs	https://doi.org/10.1021/cm970472l
State	Published - Apr 1998
Externally published	Yes

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

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title = "Synthesis and Electrooptic Properties of a New Chromophore Dispersed or Grafted in a Carbazolyl Methacrylate Matrix",

abstract = "A copolymer of [11-(N-carbazolyl)undecyl methacrylate] and ethyl (E)-2-cyano-3[5-(5-(4-methacryloyloxy)piperidino-2-thienylcarbonyl)-2-thienyl]- 2-propenoate has been prepared. The photoconductivity and the electrooptic properties of a hot-pressed thin film of this copolymer have been measured and compared with the properties of the dispersion of ethyl (E)-2-cyano-3[5-(5-piperidino-2-thienylcarbonyl)-2-thienyl]-2-propenoate within a poly[11-(N-carbazolyl)undecyl methacrylate] matrix. The electrooptic coefficient has been measured by both interferometric and polarimetric techniques. The interferometric technique was not appropriated because the strong electric field applied to the electrodes changes the film thickness of these low Tg materials. A value of up to 5 pm/V for the figure of merit n3(r13 - r33) has been reported for the dispersed material, which is 10 times higher than the corresponding grafted material, and a linear relationship between the poling intensity and the electrooptic coefficient has been observed for the two materials.",

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T1 - Synthesis and Electrooptic Properties of a New Chromophore Dispersed or Grafted in a Carbazolyl Methacrylate Matrix

AU - Maertens, C.

AU - Detrembleur, C.

AU - Dubois, P.

AU - Jérôme, R.

AU - Blanche, P. A.

AU - Lemaire, Ph C.

PY - 1998/4

Y1 - 1998/4

N2 - A copolymer of [11-(N-carbazolyl)undecyl methacrylate] and ethyl (E)-2-cyano-3[5-(5-(4-methacryloyloxy)piperidino-2-thienylcarbonyl)-2-thienyl]- 2-propenoate has been prepared. The photoconductivity and the electrooptic properties of a hot-pressed thin film of this copolymer have been measured and compared with the properties of the dispersion of ethyl (E)-2-cyano-3[5-(5-piperidino-2-thienylcarbonyl)-2-thienyl]-2-propenoate within a poly[11-(N-carbazolyl)undecyl methacrylate] matrix. The electrooptic coefficient has been measured by both interferometric and polarimetric techniques. The interferometric technique was not appropriated because the strong electric field applied to the electrodes changes the film thickness of these low Tg materials. A value of up to 5 pm/V for the figure of merit n3(r13 - r33) has been reported for the dispersed material, which is 10 times higher than the corresponding grafted material, and a linear relationship between the poling intensity and the electrooptic coefficient has been observed for the two materials.

AB - A copolymer of [11-(N-carbazolyl)undecyl methacrylate] and ethyl (E)-2-cyano-3[5-(5-(4-methacryloyloxy)piperidino-2-thienylcarbonyl)-2-thienyl]- 2-propenoate has been prepared. The photoconductivity and the electrooptic properties of a hot-pressed thin film of this copolymer have been measured and compared with the properties of the dispersion of ethyl (E)-2-cyano-3[5-(5-piperidino-2-thienylcarbonyl)-2-thienyl]-2-propenoate within a poly[11-(N-carbazolyl)undecyl methacrylate] matrix. The electrooptic coefficient has been measured by both interferometric and polarimetric techniques. The interferometric technique was not appropriated because the strong electric field applied to the electrodes changes the film thickness of these low Tg materials. A value of up to 5 pm/V for the figure of merit n3(r13 - r33) has been reported for the dispersed material, which is 10 times higher than the corresponding grafted material, and a linear relationship between the poling intensity and the electrooptic coefficient has been observed for the two materials.

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Synthesis and Electrooptic Properties of a New Chromophore Dispersed or Grafted in a Carbazolyl Methacrylate Matrix

Abstract

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