TY - JOUR
T1 - Synthesis and properties of semiconducting aromatic polyquinonediimines
AU - Everaerts, A.
AU - Roberts, Sue
AU - Hall, H. K.
PY - 1986/7
Y1 - 1986/7
N2 - A new class of poly‐conjugated polymers has been obtained by condensation of anthraquinones with aromatic diamines in polyphosphoric acid. The polymers are black, intractable powders. Toward obtaining tractable materials, the effect of monomer structure on polymer tractability has been studied. Copolymerizations were also carried out to “soften” these materials. Electrical conductivities in the semiconducting range, 10−4‐ 10−8 (ohm cm)−1 were observed. Doping with iodine showed small increases.
AB - A new class of poly‐conjugated polymers has been obtained by condensation of anthraquinones with aromatic diamines in polyphosphoric acid. The polymers are black, intractable powders. Toward obtaining tractable materials, the effect of monomer structure on polymer tractability has been studied. Copolymerizations were also carried out to “soften” these materials. Electrical conductivities in the semiconducting range, 10−4‐ 10−8 (ohm cm)−1 were observed. Doping with iodine showed small increases.
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U2 - 10.1002/pola.1986.080240727
DO - 10.1002/pola.1986.080240727
M3 - Article
AN - SCOPUS:0022755015
VL - 24
SP - 1703
EP - 1716
JO - Journal of Polymer Science, Part A: Polymer Chemistry
JF - Journal of Polymer Science, Part A: Polymer Chemistry
SN - 0887-624X
IS - 7
ER -