Synthesis of hybrid polymers using atom transfer radical polymerization: Homopolymers and block copolymers from polyhedral oligomeric silsesquioxane monomers

Dong-Chul Pyun, Krzysztof Matyjaszewski

Research output: Contribution to journalArticle

200 Citations (Scopus)

Abstract

The use of atom transfer radical polymerization (ATRP) of methacrylate functional polyhedral oligomeric silsesquioxanes (POSS) monomers is described to synthesize hybrid homopolymers and block copolymers. From this approach, homopolymers, triblock copolymers, and star-block copolymers containing POSS was prepared. While polymers containing POSS were made by other methods, using ATRP, hybrid-POSS polymers with previously unattainable compositions and drastically lower polydispersities were synthesized.

Original languageEnglish (US)
Pages (from-to)217-220
Number of pages4
JournalMacromolecules
Volume33
Issue number1
DOIs
StatePublished - Jan 11 2000
Externally publishedYes

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Atom transfer radical polymerization
Homopolymerization
Block copolymers
Polymers
Monomers
Methacrylates
Polydispersity
Stars
Chemical analysis

ASJC Scopus subject areas

  • Materials Chemistry

Cite this

Synthesis of hybrid polymers using atom transfer radical polymerization : Homopolymers and block copolymers from polyhedral oligomeric silsesquioxane monomers. / Pyun, Dong-Chul; Matyjaszewski, Krzysztof.

In: Macromolecules, Vol. 33, No. 1, 11.01.2000, p. 217-220.

Research output: Contribution to journalArticle

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