Synthesis of organic/inorganic hybrid materials using atom transfer radical polymerization

Dong-Chul Pyun, Peter J. Miller, Krzvsztof Matyjaszewski

Research output: Chapter in Book/Report/Conference proceedingChapter

3 Citations (Scopus)

Abstract

Atom transfer radical polymerization (ATRP), using inorganic macroinitiators or monomers is a versatile method to prepare organic/inorganic hybrid materials. ATRP was used to synthesize a variety of well-defined (co)polymers from acrylates, methacrylates and styrenes. Due to its radical nature, a wide range of monomers and polymers can be employed, provided that interaction with the catalyst is avoided. By incorporating an activated alkyl halide group into the targeted inorganic polymer or substrate, poly(dimethylsiloxane) and silicon wafers, functionalized with initiator groups, was used as initiator for ATRP. Similarly, polyhedral oligomeric silsesquioxane monomers were used to prepare hybrid materials by ATRP.

Original languageEnglish (US)
Title of host publicationAmerican Chemical Society, Polymer Preprints, Division of Polymer Chemistry
PublisherACS
Pages536-537
Number of pages2
Volume41
Edition1
StatePublished - Mar 2000
Externally publishedYes
EventThe San Francisco Meeting - San Francisco, CA, USA
Duration: Mar 26 2000Mar 31 2000

Other

OtherThe San Francisco Meeting
CitySan Francisco, CA, USA
Period3/26/003/31/00

Fingerprint

Atom transfer radical polymerization
Hybrid materials
Monomers
Polymers
Styrenes
Acrylates
Inorganic polymers
Methacrylates
Polydimethylsiloxane
Silicon wafers
Styrene
Catalysts
Substrates

ASJC Scopus subject areas

  • Polymers and Plastics

Cite this

Pyun, D-C., Miller, P. J., & Matyjaszewski, K. (2000). Synthesis of organic/inorganic hybrid materials using atom transfer radical polymerization. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry (1 ed., Vol. 41, pp. 536-537). ACS.

Synthesis of organic/inorganic hybrid materials using atom transfer radical polymerization. / Pyun, Dong-Chul; Miller, Peter J.; Matyjaszewski, Krzvsztof.

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 41 1. ed. ACS, 2000. p. 536-537.

Research output: Chapter in Book/Report/Conference proceedingChapter

Pyun, D-C, Miller, PJ & Matyjaszewski, K 2000, Synthesis of organic/inorganic hybrid materials using atom transfer radical polymerization. in American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 1 edn, vol. 41, ACS, pp. 536-537, The San Francisco Meeting, San Francisco, CA, USA, 3/26/00.
Pyun D-C, Miller PJ, Matyjaszewski K. Synthesis of organic/inorganic hybrid materials using atom transfer radical polymerization. In American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 1 ed. Vol. 41. ACS. 2000. p. 536-537
Pyun, Dong-Chul ; Miller, Peter J. ; Matyjaszewski, Krzvsztof. / Synthesis of organic/inorganic hybrid materials using atom transfer radical polymerization. American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. Vol. 41 1. ed. ACS, 2000. pp. 536-537
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