Synthesis of Polymer Brushes Using Atom Transfer Radical Polymerization

Dong-Chul Pyun, Tomasz Kowalewski, Krzysztof Matyjaszewski

Research output: Contribution to journalArticle

620 Citations (Scopus)

Abstract

Atom transfer radical polymerization (ATRP) is a robust method for the preparation of (co)polymers. This process has also enabled the preparation of a wide range of polymer brushes where (co)polymers are covalently attached to either curved or flat surfaces. In this review, the general methodology for the synthesis of polymer brushes from flat surfaces, polymers and colloids is summarized focusing on reports using ATRP. Additionally, the morphology of ultrathin films from polymer brushes is discussed using atomic force microscopy (AFM) and other techniques to confirm the formation of nanoscale structure and organization.

Original languageEnglish (US)
Pages (from-to)1043-1059
Number of pages17
JournalMacromolecular Rapid Communications
Volume24
Issue number18
DOIs
StatePublished - Dec 8 2003
Externally publishedYes

Fingerprint

Atom transfer radical polymerization
Brushes
Polymers
Ultrathin films
Colloids
Atomic force microscopy

Keywords

  • Atom transfer radical polymerization (ATRP)
  • Atomic force microscopy (AFM)
  • Interfaces
  • Nanocomposites
  • Polymer brushes

ASJC Scopus subject areas

  • Polymers and Plastics
  • Materials Chemistry

Cite this

Synthesis of Polymer Brushes Using Atom Transfer Radical Polymerization. / Pyun, Dong-Chul; Kowalewski, Tomasz; Matyjaszewski, Krzysztof.

In: Macromolecular Rapid Communications, Vol. 24, No. 18, 08.12.2003, p. 1043-1059.

Research output: Contribution to journalArticle

Pyun, Dong-Chul ; Kowalewski, Tomasz ; Matyjaszewski, Krzysztof. / Synthesis of Polymer Brushes Using Atom Transfer Radical Polymerization. In: Macromolecular Rapid Communications. 2003 ; Vol. 24, No. 18. pp. 1043-1059.
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