The lowest singlet and triplet states of the oxyallyl diradical

Takatoshi Ichino, Stephanie M. Villano, Adam J. Gianola, Daniel J. Goebbert, Andrei M Sanov, Luis Velarde, Stephen J. Blanksby, Xin Zhou, David A. Hrovat, Weston Thatcher Borden, W. Carl Lineberger

Research output: Contribution to journalArticle

62 Citations (Scopus)

Abstract

Small S-T splitting: The photoelectron spectrum of the oxyallyl radical anion (see picture) reveals that the electronic ground state of oxyallyl is singlet, and the lowest triplet state is separated from the singlet state by only (55 ± 2) meV in adiabatic energy.

Original languageEnglish (US)
Pages (from-to)8509-8511
Number of pages3
JournalAngewandte Chemie - International Edition
Volume48
Issue number45
DOIs
StatePublished - Oct 26 2009

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Photoelectrons
Ground state
Anions
Negative ions

Keywords

  • Oxyallyl compounds
  • Photoelectron spectroscopy
  • Radicals
  • Reactive intermediates

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis

Cite this

Ichino, T., Villano, S. M., Gianola, A. J., Goebbert, D. J., Sanov, A. M., Velarde, L., ... Carl Lineberger, W. (2009). The lowest singlet and triplet states of the oxyallyl diradical. Angewandte Chemie - International Edition, 48(45), 8509-8511. https://doi.org/10.1002/anie.200904417

The lowest singlet and triplet states of the oxyallyl diradical. / Ichino, Takatoshi; Villano, Stephanie M.; Gianola, Adam J.; Goebbert, Daniel J.; Sanov, Andrei M; Velarde, Luis; Blanksby, Stephen J.; Zhou, Xin; Hrovat, David A.; Borden, Weston Thatcher; Carl Lineberger, W.

In: Angewandte Chemie - International Edition, Vol. 48, No. 45, 26.10.2009, p. 8509-8511.

Research output: Contribution to journalArticle

Ichino, T, Villano, SM, Gianola, AJ, Goebbert, DJ, Sanov, AM, Velarde, L, Blanksby, SJ, Zhou, X, Hrovat, DA, Borden, WT & Carl Lineberger, W 2009, 'The lowest singlet and triplet states of the oxyallyl diradical', Angewandte Chemie - International Edition, vol. 48, no. 45, pp. 8509-8511. https://doi.org/10.1002/anie.200904417
Ichino, Takatoshi ; Villano, Stephanie M. ; Gianola, Adam J. ; Goebbert, Daniel J. ; Sanov, Andrei M ; Velarde, Luis ; Blanksby, Stephen J. ; Zhou, Xin ; Hrovat, David A. ; Borden, Weston Thatcher ; Carl Lineberger, W. / The lowest singlet and triplet states of the oxyallyl diradical. In: Angewandte Chemie - International Edition. 2009 ; Vol. 48, No. 45. pp. 8509-8511.
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