The millimeter-wave spectrum of the SrOH and SrOD radicals

M. A. Anderson, W. L. Barclay, L. M. Ziurys

Research output: Contribution to journalArticle

39 Scopus citations

Abstract

The pure rotational spectra of the X 2Σ+ ground states of the SrOH and SrOD radicals have been observed in the laboratory using millimeter/submillimeter direct absorption spectroscopy. The lesser abundant isotopically substituted species, 86SrOH, has been observed as well. The molecules were produced in a Broida-type oven by the reaction of Sr metal vapor with either H2O2 or D2O2. The rotational and spin-rotation constants were determined for the radicals from a nonlinear least-squares fit to the data using a 2Σ Hamiltonian. The millimeter-wave measurements support the picture that strontium hydroxide is linear in its ground electronic and vibrational state.

Original languageEnglish (US)
Pages (from-to)166-172
Number of pages7
JournalChemical Physics Letters
Volume196
Issue number1-2
DOIs
StatePublished - Aug 7 1992
Externally publishedYes

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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