The millimeter/sub-millimeter spectrum of the LiS radical in its 2Πi ground state

M. A. Brewster, L. M. Ziurys

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11 Scopus citations

Abstract

The pure rotational spectrum of LiS (X2Πi) has been recorded in the v=0 and v=1 states in the region 130-540 GHz using millimeter/sub-millimeter direct absorption methods. This radical was synthesized from lithium vapor and CS2 in a DC discharge. Transitions arising from the two orbit components were measured, both which exhibited lambda-doubling and, for the Ω=1/2 ladder, hyperfine interactions. Rotational, lambda-doubling, and hyperfine parameters have subsequently been determined. These data prove unambiguously that the ground state of LiS is 2Πi and suggest that the A2Σ+ state lies ~4300cm-1 higher in energy. The bonding in this radical appears to be predominantly ionic.

Original languageEnglish (US)
Pages (from-to)249-256
Number of pages8
JournalChemical Physics Letters
Volume349
Issue number3-4
DOIs
StatePublished - Nov 30 2001

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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