The pure rotational spectrum of TiF (X4Φr): 3 d transition metal fluorides revisited

P. M. Sheridan, S. K. McLamarrah, L. M. Ziurys

Research output: Contribution to journalArticle

16 Scopus citations

Abstract

The first measurement of the pure rotational spectrum of the TiF radical using millimeter/sub-mm direct absorption methods is presented. The given data is modeled using a Hund's case (a) effective Hamiltonian, leading to the determination of rotational, fine structure, and hyperfine parameters. This paper presents the results, interpret the constants and discuss their implications for bonding in 3d transition metal fluorides.

Original languageEnglish (US)
Pages (from-to)9496-9503
Number of pages8
JournalJournal of Chemical Physics
Volume119
Issue number18
DOIs
StatePublished - Nov 8 2003

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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