The pure rotational spectrum of TiF (X4Φr): 3 d transition metal fluorides revisited

P. M. Sheridan, S. K. McLamarrah, Lucy M Ziurys

Research output: Contribution to journalArticle

16 Citations (Scopus)

Abstract

The first measurement of the pure rotational spectrum of the TiF radical using millimeter/sub-mm direct absorption methods is presented. The given data is modeled using a Hund's case (a) effective Hamiltonian, leading to the determination of rotational, fine structure, and hyperfine parameters. This paper presents the results, interpret the constants and discuss their implications for bonding in 3d transition metal fluorides.

Original languageEnglish (US)
Pages (from-to)9496-9503
Number of pages8
JournalThe Journal of Chemical Physics
Volume119
Issue number18
DOIs
StatePublished - Nov 8 2003

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metal fluorides
Hamiltonians
rotational spectra
Fluorides
Transition metals
transition metals
fine structure

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

The pure rotational spectrum of TiF (X4Φr) : 3 d transition metal fluorides revisited. / Sheridan, P. M.; McLamarrah, S. K.; Ziurys, Lucy M.

In: The Journal of Chemical Physics, Vol. 119, No. 18, 08.11.2003, p. 9496-9503.

Research output: Contribution to journalArticle

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