The rotational spectrum and theoretical study of a dinuclear complex, MnRe(CO) 10

Chakree Tanjaroon, Kristen S. Keck, Stephen G Kukolich, Michael H. Palmer, Martyn F. Guest

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The rotational spectrum of a dinuclear complex was studied using high-resolution pulsed beam microwave spectrometers. The rotational spectrum of MnRe(CO) 10 were measured and analyzed to obtain the gas phase molecular parameters of the complex. It was observed that the solid phase could be due to the presence of the crystal packing forces in the crystal. The results suggest that the Mn-Re bond is slightly larger than the sum of the covalent radii.

Original languageEnglish (US)
Pages (from-to)4715-4725
Number of pages11
JournalThe Journal of Chemical Physics
Volume120
Issue number10
DOIs
StatePublished - Mar 8 2004

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rotational spectra
Carbon Monoxide
Microwave spectrometers
microwave spectrometers
Crystals
crystals
solid phases
Gases
vapor phases
radii
high resolution

ASJC Scopus subject areas

  • Atomic and Molecular Physics, and Optics

Cite this

The rotational spectrum and theoretical study of a dinuclear complex, MnRe(CO) 10 . / Tanjaroon, Chakree; Keck, Kristen S.; Kukolich, Stephen G; Palmer, Michael H.; Guest, Martyn F.

In: The Journal of Chemical Physics, Vol. 120, No. 10, 08.03.2004, p. 4715-4725.

Research output: Contribution to journalArticle

Tanjaroon, Chakree ; Keck, Kristen S. ; Kukolich, Stephen G ; Palmer, Michael H. ; Guest, Martyn F. / The rotational spectrum and theoretical study of a dinuclear complex, MnRe(CO) 10 In: The Journal of Chemical Physics. 2004 ; Vol. 120, No. 10. pp. 4715-4725.
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