The Si-Si effect on ionization of β-disilanyl sulfides and selenides

Richard S. Glass, Eric Block, Edward Lorance, Uzma I. Zakai, Nadine E. Gruhn, Jin Jin, Shao Zhong Zhang

Research output: Contribution to journalArticle

13 Scopus citations

Abstract

The ionization energies of conformationally constrained, newly synthesized β-disilanyl sulfides and selenides were determined by photoelectron spectroscopy. These ionization energies reflect substantial (0.53-0.75 eV) orbital destabilizations. The basis for these destabilizations was investigated by theoretical calculations, which reveal geometry-dependent interaction between sulfur or selenium lone pair orbitals and σ-orbitals, especially Si-Si σ-orbitals. These results presage facile redox chemistry for these compounds and significantly extend the concept of σ-stabilization of electron-deficient centers.

Original languageEnglish (US)
Pages (from-to)12685-12692
Number of pages8
JournalJournal of the American Chemical Society
Volume128
Issue number39
DOIs
StatePublished - Oct 4 2006

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ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Glass, R. S., Block, E., Lorance, E., Zakai, U. I., Gruhn, N. E., Jin, J., & Zhang, S. Z. (2006). The Si-Si effect on ionization of β-disilanyl sulfides and selenides. Journal of the American Chemical Society, 128(39), 12685-12692. https://doi.org/10.1021/ja0573514