Abstract
The synthesis and characterization of thermally labile dendronized linear AB step-polymers is described. First through third generation dendritic AB monomers 14a-c containing both a furan and furan-protected maleimide functionality were prepared by the Cu(I)-catalyzed azide-alkyne cycloaddition reaction followed by polymerization via the thermally reversible furan-maleimide Diels-Alder reaction. The assembly, disassembly, and reassembly behavior of linear dendronized step-polymers 16a-c was studied by GPC.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 3203-3210 |
| Number of pages | 8 |
| Journal | Macromolecules |
| Volume | 44 |
| Issue number | 9 |
| DOIs | |
| State | Published - May 10 2011 |
Fingerprint
ASJC Scopus subject areas
- Organic Chemistry
- Materials Chemistry
- Polymers and Plastics
- Inorganic Chemistry
Cite this
Thermally reversible dendronized linear ab step-polymers via "click" chemistry. / Polaske, Nathan W.; Mcgrath, Dominic V; McElhanon, James R.
In: Macromolecules, Vol. 44, No. 9, 10.05.2011, p. 3203-3210.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Thermally reversible dendronized linear ab step-polymers via "click" chemistry
AU - Polaske, Nathan W.
AU - Mcgrath, Dominic V
AU - McElhanon, James R.
PY - 2011/5/10
Y1 - 2011/5/10
N2 - The synthesis and characterization of thermally labile dendronized linear AB step-polymers is described. First through third generation dendritic AB monomers 14a-c containing both a furan and furan-protected maleimide functionality were prepared by the Cu(I)-catalyzed azide-alkyne cycloaddition reaction followed by polymerization via the thermally reversible furan-maleimide Diels-Alder reaction. The assembly, disassembly, and reassembly behavior of linear dendronized step-polymers 16a-c was studied by GPC.
AB - The synthesis and characterization of thermally labile dendronized linear AB step-polymers is described. First through third generation dendritic AB monomers 14a-c containing both a furan and furan-protected maleimide functionality were prepared by the Cu(I)-catalyzed azide-alkyne cycloaddition reaction followed by polymerization via the thermally reversible furan-maleimide Diels-Alder reaction. The assembly, disassembly, and reassembly behavior of linear dendronized step-polymers 16a-c was studied by GPC.
UR - http://www.scopus.com/inward/record.url?scp=79955658834&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=79955658834&partnerID=8YFLogxK
U2 - 10.1021/ma200296t
DO - 10.1021/ma200296t
M3 - Article
AN - SCOPUS:79955658834
VL - 44
SP - 3203
EP - 3210
JO - Macromolecules
JF - Macromolecules
SN - 0024-9297
IS - 9
ER -