Thermally reversible dendronized linear ab step-polymers via "click" chemistry

Nathan W. Polaske, Dominic V Mcgrath, James R. McElhanon

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

The synthesis and characterization of thermally labile dendronized linear AB step-polymers is described. First through third generation dendritic AB monomers 14a-c containing both a furan and furan-protected maleimide functionality were prepared by the Cu(I)-catalyzed azide-alkyne cycloaddition reaction followed by polymerization via the thermally reversible furan-maleimide Diels-Alder reaction. The assembly, disassembly, and reassembly behavior of linear dendronized step-polymers 16a-c was studied by GPC.

Original languageEnglish (US)
Pages (from-to)3203-3210
Number of pages8
JournalMacromolecules
Volume44
Issue number9
DOIs
StatePublished - May 10 2011

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Polymers
Cycloaddition
Alkynes
Azides
Monomers
Polymerization
furan
maleimide

ASJC Scopus subject areas

  • Organic Chemistry
  • Materials Chemistry
  • Polymers and Plastics
  • Inorganic Chemistry

Cite this

Thermally reversible dendronized linear ab step-polymers via "click" chemistry. / Polaske, Nathan W.; Mcgrath, Dominic V; McElhanon, James R.

In: Macromolecules, Vol. 44, No. 9, 10.05.2011, p. 3203-3210.

Research output: Contribution to journalArticle

Polaske, Nathan W. ; Mcgrath, Dominic V ; McElhanon, James R. / Thermally reversible dendronized linear ab step-polymers via "click" chemistry. In: Macromolecules. 2011 ; Vol. 44, No. 9. pp. 3203-3210.
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