Thermally reversible dendronized linear ab step-polymers via "click" chemistry

Nathan W. Polaske; Dominic V. McGrath; James R. McElhanon

doi:10.1021/ma200296t

Thermally reversible dendronized linear ab step-polymers via "click" chemistry

Nathan W. Polaske, Dominic V. McGrath, James R. McElhanon

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

25 Scopus citations

Abstract

The synthesis and characterization of thermally labile dendronized linear AB step-polymers is described. First through third generation dendritic AB monomers 14a-c containing both a furan and furan-protected maleimide functionality were prepared by the Cu(I)-catalyzed azide-alkyne cycloaddition reaction followed by polymerization via the thermally reversible furan-maleimide Diels-Alder reaction. The assembly, disassembly, and reassembly behavior of linear dendronized step-polymers 16a-c was studied by GPC.

Original language	English (US)
Pages (from-to)	3203-3210
Number of pages	8
Journal	Macromolecules
Volume	44
Issue number	9
DOIs	https://doi.org/10.1021/ma200296t
State	Published - May 10 2011

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma200296t

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AU - Polaske, Nathan W.

AU - McGrath, Dominic V.

AU - McElhanon, James R.

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N2 - The synthesis and characterization of thermally labile dendronized linear AB step-polymers is described. First through third generation dendritic AB monomers 14a-c containing both a furan and furan-protected maleimide functionality were prepared by the Cu(I)-catalyzed azide-alkyne cycloaddition reaction followed by polymerization via the thermally reversible furan-maleimide Diels-Alder reaction. The assembly, disassembly, and reassembly behavior of linear dendronized step-polymers 16a-c was studied by GPC.

AB - The synthesis and characterization of thermally labile dendronized linear AB step-polymers is described. First through third generation dendritic AB monomers 14a-c containing both a furan and furan-protected maleimide functionality were prepared by the Cu(I)-catalyzed azide-alkyne cycloaddition reaction followed by polymerization via the thermally reversible furan-maleimide Diels-Alder reaction. The assembly, disassembly, and reassembly behavior of linear dendronized step-polymers 16a-c was studied by GPC.

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Thermally reversible dendronized linear ab step-polymers via "click" chemistry

Abstract

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