Abstract
The synthesis and characterization of thermally labile dendronized linear AB step-polymers is described. First through third generation dendritic AB monomers 14a-c containing both a furan and furan-protected maleimide functionality were prepared by the Cu(I)-catalyzed azide-alkyne cycloaddition reaction followed by polymerization via the thermally reversible furan-maleimide Diels-Alder reaction. The assembly, disassembly, and reassembly behavior of linear dendronized step-polymers 16a-c was studied by GPC.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 3203-3210 |
| Number of pages | 8 |
| Journal | Macromolecules |
| Volume | 44 |
| Issue number | 9 |
| DOIs | |
| State | Published - May 10 2011 |
ASJC Scopus subject areas
- Organic Chemistry
- Polymers and Plastics
- Inorganic Chemistry
- Materials Chemistry
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Polaske, N. W., McGrath, D. V., & McElhanon, J. R. (2011). Thermally reversible dendronized linear ab step-polymers via "click" chemistry. Macromolecules, 44(9), 3203-3210. https://doi.org/10.1021/ma200296t