U-Th zonation-dependent alpha-ejection in (U-Th)/He chronometry

Jeremy K. Hourigan, Peter W Reiners, Mark T. Brandon

Research output: Contribution to journalArticle

225 Citations (Scopus)

Abstract

Both theoretical and empirical evidence shows that intracrystalline U-Th heterogeneity in zircon can lead to biases in (U-Th)/He ages if not accurately accounted for in α-ejection corrections. We present a model for age correction for U-Th zoned crystals. We apply this to spherical and prismatic grains with bipyramidal terminations. The spherical calculation is simplistic but allows rapid calculation of the approximate effects of a wide variety of U-Th zoning patterns. The bipyramidal calculation is computationally intensive but permits an more complete estimate of the combined effects of crystal morphology and source zoning as relevant to zircon. Our principle findings are: (1) the assumption of U-Th homogeneity can result in errors of up to ∼30% (in rare cases, higher) for ejection-corrected ages for typical grain sizes and realistic zonation. (2) Tetragonal prisms with bipyramidal terminations, which are typical of most zircons, exhibit bulk retentivities that can differ by several percent from models considering crystals with pinacoidal terminations. When extreme cases, such as dipyramids, are considered, the bias can exceed 10% or more. (3) Morphologic effects can be accounted for to better than 1% precision by using new second-order polynomial parameters that describe retentivity as a function of surface-area-to-volume ratio calculated through more complete analysis of crystal dimensions including the height of pyramidal crystal sections. We illustrate application of our model using U-Th concentration profiles determined from single zircons by laser ablation ICP-MS from zoned Tardree Rhyolite zircons.

Original languageEnglish (US)
Pages (from-to)3349-3365
Number of pages17
JournalGeochimica et Cosmochimica Acta
Volume69
Issue number13
DOIs
StatePublished - Jul 1 2005
Externally publishedYes

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zonation
zircon
crystal
Crystals
Zoning
zoning
Laser ablation
Prisms
rhyolite
ablation
homogeneity
grain size
surface area
laser
Polynomials
calculation
effect

ASJC Scopus subject areas

  • Geochemistry and Petrology

Cite this

U-Th zonation-dependent alpha-ejection in (U-Th)/He chronometry. / Hourigan, Jeremy K.; Reiners, Peter W; Brandon, Mark T.

In: Geochimica et Cosmochimica Acta, Vol. 69, No. 13, 01.07.2005, p. 3349-3365.

Research output: Contribution to journalArticle

Hourigan, Jeremy K. ; Reiners, Peter W ; Brandon, Mark T. / U-Th zonation-dependent alpha-ejection in (U-Th)/He chronometry. In: Geochimica et Cosmochimica Acta. 2005 ; Vol. 69, No. 13. pp. 3349-3365.
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