Understanding the role of atomic hydrogen on chloroethene reactions at iron surfaces

Jiankang Wang, James Farrell

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

There has been increasing interest in using metallic iron fillings for remediating groundwater contaminated by chlorinated solvents. The role of atomic hydrogen in reductive dechlorination of trichloroethylene (TCE) and tetrachloroethylene (PCE) was studied. At pH = 7, TCE reaction rates were 2 ± 0.26 times faster than those for PCE when each was present at 6 μM concentration, and were 1.5 ± 0.15 times faster at 30 μM concentration. The reaction mechanism involving atomic hydrogen could be saturated at low TCE concentrations. Thus, at neutral pH values reduction by atomic hydrogen could be the dominant TCE reduction pathway only at very low TCE concentrations.

Original languageEnglish (US)
Title of host publicationACS Division of Environmental Chemistry, Preprints
Volume43
Edition2
StatePublished - 2003

Fingerprint

Trichloroethylene
Hydrogen
Iron
Tetrachloroethylene
Dechlorination
Reaction rates
Groundwater

ASJC Scopus subject areas

  • Chemical Engineering(all)

Cite this

Wang, J., & Farrell, J. (2003). Understanding the role of atomic hydrogen on chloroethene reactions at iron surfaces. In ACS Division of Environmental Chemistry, Preprints (2 ed., Vol. 43)

Understanding the role of atomic hydrogen on chloroethene reactions at iron surfaces. / Wang, Jiankang; Farrell, James.

ACS Division of Environmental Chemistry, Preprints. Vol. 43 2. ed. 2003.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Wang, J & Farrell, J 2003, Understanding the role of atomic hydrogen on chloroethene reactions at iron surfaces. in ACS Division of Environmental Chemistry, Preprints. 2 edn, vol. 43.
Wang J, Farrell J. Understanding the role of atomic hydrogen on chloroethene reactions at iron surfaces. In ACS Division of Environmental Chemistry, Preprints. 2 ed. Vol. 43. 2003
Wang, Jiankang ; Farrell, James. / Understanding the role of atomic hydrogen on chloroethene reactions at iron surfaces. ACS Division of Environmental Chemistry, Preprints. Vol. 43 2. ed. 2003.
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