Using 17O to investigate nitrate sources and sinks in a semi-arid groundwater system

Navid René Dejwakh, Thomas Meixner, Greg Michalski, Jennifer McIntosh

Research output: Contribution to journalArticle

21 Scopus citations

Abstract

We apply a triple isotope approach for nitrate that utilizes Δ 17O as a conservative tracer, in combination with δ 18O and δ 15N, to assess source/sink dynamics of groundwater nitrate beneath alluvial washes in a semiarid urban setting. Other studies have used δ 18O and δ 15N to determine nitrate sources and cycling, but the atmospheric δ 18O signature can be overprinted by biogeochemical processes. In this study, δ 18O and δ 15N values of nitrate were coupled with δ 17O values of nitrate to quantify atmospheric nitrate inputs and denitrification amounts. Results show generally low groundwater nitrate concentrations (<0.2 mmol/L) throughout the basin; high nitrate concentrations (up to 1 mmol/L) with evidence for some denitrification were detected in areas where effluent was the predominant source of recharge to groundwater. Furthermore, the denitrification was inferred from elevated δ 18O and δ 15N values which were reinforced by increases in observed δ 17O values. Finally, relatively low, but significant atmospheric nitrate concentrations were measured in groundwater (up to 6% of total nitrate). This study concludes that the triple isotope approach improves determination of the proportion of atmospheric nitrate and the significance of denitrification in natural waters, allowing us to develop a conceptual model of the biogeochemical processes controlling nitrogen in an urban setting.

Original languageEnglish (US)
Pages (from-to)745-751
Number of pages7
JournalEnvironmental Science and Technology
Volume46
Issue number2
DOIs
StatePublished - Jan 17 2012

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry

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